3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Names and Identifiers

Name	Procymidone
Synonyms	ISO BSI s7131 Sumilex PROMIDON sp751011 DICYCLIDINE Procymidone procymidone (bsi,iso,jmaf) 1,2-dimethyl-N-(3,5-dichlorophenyl)cyclopropanedicarboximide n-(3,5-dichlorophenyl)-1,2-dimethyl-2-cyclopropanedicarboximide N-(3,5-dichlorophenyl)-1,2-dimethylcyclopropane-1,2-dicarboximide n-(3,5-dichlorophenyl)-1,2-dimethyl-1,2-cyclopropanedicarboximide 1,2-Cyclopropanedicarboximide, N-(3,5-dichlorophenyl)-1,2-dimethyl- 3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo(3.1.0)hexane-4-dione 3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione 3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo(3.1.0)hexane-2,4-dione 3-azabicyclo[3.1.0]hexane-2,4-dione,3-(3,5-dichlorophenyl)-1,5-dimethyl-
CAS	32809-16-8
EINECS	251-233-1
InChI	InChI=1/C13H11Cl2NO2/c1-12-6-13(12,2)11(18)16(10(12)17)9-4-7(14)3-8(15)5-9/h3-5H,6H2,1-2H3
InChIKey	QXJKBPAVAHBARF-UHFFFAOYSA-N

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Physico-chemical Properties

Molecular Formula	C13H11Cl2NO2
Molar Mass	284.14
Density	d25 1.42-1.46
Melting Point	166-167°C
Boling Point	477.9±35.0 °C(Predicted)
Flash Point	>100°C
Water Solubility	4.5 mg l-1 (25 °C)
Solubility	Chloroform (Slightly), Ethyl Acetate (Slightly)
Vapor Presure	1.8 x 10-2 Pa (25 °C)
Appearance	neat
Color	Off-White to Pale Beige
BRN	1539058
pKa	-2.67±0.60(Predicted)
Storage Condition	Sealed in dry,Room Temperature
Refractive Index	1.6100 (estimate)
Physical and Chemical Properties	pure white crystals, m.p.166 -166.5 °c, relative density 1.42-1.46 (25 °c), vapor pressure 1.05 × 10-2Pa (20 °c), 17.59 × 10-3Pa (25 °c). Soluble in acetone, chloroform, xylene, dimethylformamide, ethanol-soluble, insoluble in water. Under normal conditions, storage is stable for 2 years, stable under acidic conditions, easy to decompose in case of alkali, industrial products are white or light brown crystals.
Use	Inhalation of fungicides, both the role of protection and treatment, the use of low temperature and high humidity conditions, the effect is obvious. For rape, radish, eggplant, cucumber, cabbage, tomato, sunflower, watermelon, strawberry, onion, peach, cherry, flowers, grapes and other crops, control Botrytis cinerea and Sclerotinia sclerotiorum and Gray Star Disease, flower rot disease, brown rot, Vine blight, can also be used for thiophanate-methyl, carbendazim resistant original bacteria. Such as the prevention and control of gray mold, in the early flowering stage, flowering stage, fruit stage respectively with 50% wettable powder 1000~2000 times liquid spray; Prevention and control of Sclerotinia sclerotiorum in the early stage, spray with 50% ~ 1500 times of 2000 wettable powder, spray 1~2 times in the early flowering period and flowering period. For the prevention and control of tomato gray mold and other diseases in protected areas

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Risk and Safety

WGK Germany	2
RTECS	GZ2150000
HS Code	29251900
Toxicity	LD50 in male rats (mg/kg): 6800 orally, >10000 dermally (Jackson); LD50 in male, female rats (g/kg): 7.8, 9.1 orally (Mikami)

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Upstream Downstream Industry

Raw Materials

3,5-Dichloroaniline

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Reference Information

NIST chemical information	Information provided by: webbook.nist.gov (external link)
EPA chemical information	Information provided by: ofmpub.epa.gov (external link)
toxicity	acute oral LD506800mg/kg in male rats, 7700 mg/kg in female rats, 7800 mg/kg in male mice and 9100 mg/kg in female mice. Acute percutaneous LD50>2500mg/kg in large and mouse. LD50>10000mg/kg was injected subcutaneously in rats and mice. LD50850mg/kg was injected intraperitoneally into male rats and 730 mg/kg into female rats. The subacute oral dose of 22.0 mg/kg in male mice and 83.5 mg/kg in female mice. Feeding rats with a dose of 1000mg/kg for 12 months, there was no weight loss, no abnormality in clinical blood chemical parameters, no abnormality in urine analysis, and no pathological changes in ophthalmic examination. No teratogenic and mutagenic effects were found in animal tests, and no adverse effects were found in three generations of reproductive tests. Carp LC50>10mg/L(48h), rainbow trout LC507.22 mg/L (96h), blue gill LC5010.25 mg/L (96h), safe for birds and bees.
use	systemic fungicide has both protective and therapeutic effects, and the use effect is obvious under low temperature and high humidity conditions. Used for rape, radish, eggplant, cucumber, cabbage, tomato, sunflower, watermelon, strawberry, onion, peach, cherry, flower, grape and other crops to prevent gray mold and sclerotinia and gray star disease, flower rot, Brown rot, vine blight, etc., can also be used to resist thiophanate-methyl and carbendazim. For the prevention and control of gray mold, spray 1000~2000 times of 50% wettable powder at the early flowering stage, full flowering stage, and fruiting stage; for the prevention and control of sclerotinia sclerotiorum, spray 1500~2000 times of 50% wettable powder at the early flowering stage and full flowering stage. It is a vegetable fungicide for protection The systemic fungicide has both protective and therapeutic effects, and the effect is obvious under low temperature and high humidity conditions. Used for rape, radish, eggplant, cucumber, cabbage, tomato, sunflower, watermelon, strawberry, onion, peach, cherry, flower, grape and other crops to prevent gray mold and sclerotinia and gray star disease, flower rot, Brown rot, vine blight, etc., can also be used to resist thiophanate-methyl and carbendazim. For the prevention and control of gray mold, spray 1000~2000 times of 50% wettable powder at the early flowering stage, full flowering stage, and fruiting stage; for the prevention and control of sclerotinia sclerotiorum, spray 1500~2000 times of 50% wettable powder at the early flowering stage and full flowering stage. Used to prevent and control diseases such as tomato gray mold in protected areas rape, cucumber sclerotium, grape, tomato, strawberry, cucumber gray mold, fruit tree brown spot, corn size spot, tomato early blight.
production method	preparation method 1 is made of methyl α-chloropropionate, methyl α-methacrylate and 3, 5-dichloroaniline as raw materials. First, methyl α-chloropropionate and α-methyl methacrylate were reacted to prepare 1, 2-dimethylcyclopropane-1, 2-diformate methyl, and then hydrolyzed to obtain 1, 2-Dimethylcyclopropane-1, 2-dicarboxylic acid. The above products are reacted with 3, 5-dichloroaniline to synthesize promethaniline. Preparation method Ethyl diα-methacrylate reacts with ethyl α-chloropropionate, potassium butanol, sodium hydroxide and acetic anhydride to prepare 1, 2-dimethylcyclopropane -1, 2-dicarboxylic anhydride. Then add the benzene solution of 3,5-dichloroaniline dropwise, precipitate the intermediate, stir for 30min after dropping, debenzene under reduced pressure, add acetic anhydride and anhydrous sodium acetate to the residue, heat at 100 ℃ for 30-60min, remove acetic acid and excess acetic anhydride, wash with dilute sodium hydroxide and water, and dry to obtain Pythium. M. p.165 ~ 167 ℃.
category	pesticide
toxicity classification	low toxicity
acute toxicity	oral-rat LD50: 7000 mg/kg; Oral-mouse LD50: 7800 mg/kg
flammability hazard characteristics	Combustion produces toxic nitrogen oxides and chloride gases
storage and transportation characteristics	warehouse ventilation and low temperature drying; separate from food raw materials storage and transportation
fire extinguishing agent	dry powder, foam, sand

Last Update：2024-04-09 15:16:49

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione

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CAS: 32809-16-8
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CAS: 32809-16-8
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Hefei TNJ Chemical Industry Co.,Ltd.

Product Name: Procymidone Request for quotation
CAS: 32809-16-8
Tel: 0086-551-65418684
Email: sales@tnjchem.com
　　　　 info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840

Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog

Shanghai Yuanye Bio-Technology Co., Ltd.

Multiple Specifications

Product Name: Procymidone Visit Supplier Webpage Request for quotation
CAS: 32809-16-8
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409

Wechat: 18301782025

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3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione

Raw Materials for 3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione

3,5-Dichloroaniline

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione

Procymidone

CAS: 32809-16-8

Molecular Formula: C13H11Cl2NO2

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Names and Identifiers

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Physico-chemical Properties

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Risk and Safety

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Upstream Downstream Industry

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Reference Information

Supplier List

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione Request for Quotation

Procymidone

CAS: 32809-16-8

Molecular Formula: C13H11Cl2NO2

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Names and Identifiers

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Physico-chemical Properties

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Risk and Safety

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Upstream Downstream Industry

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione - Reference Information

Supplier List

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione